Heat Transfer Fluids

Thermosol Concentrate

Non-toxic antifreeze for high temperatures, based on high-boiling-point glycols, for evacuated tube collectors.
Properties | Antifreeze, Biodegradable, Concentrate, Non-toxic
Sectors | Data Centers, Electric Generators, ENERGY, ENGINES, GENERAL INDUSTRY, Geothermal, Industrial Cooling, Light & Heavy Duty, Solar Thermal, Transformer

Description

Thermosol® Concentrate is a product formulated with high-boiling-point glycols that offer excellent resistance to degradation at high temperatures. It withstands high thermal loads, retaining its properties for longer than antifreeze products based on monoethylene glycol or propylene glycol.

The state-of-the-art organic additives used in this product keep the circuit in perfect working order for longer periods than conventional inorganic products.

The product protects the metal components typically found in thermal circuits. It optimizes heat transfer and thus improves system performance.

Its red color makes it easy to detect leaks in the system. Thanks to its formulation based on non-toxic glycol, it is safe to handle.

It contains no nitrites or amines, substances that can form nitrosamines, i.e. potential carcinogens. It contains no phosphates or borates, which have come under scrutiny due to their harmful impact on the environment. It contains no silicates, nitrates, 2EH or heavy metals.

Packaging formats

Advantages

  • Prevents damage to the circuit caused by freezing.
  • Raises the boiling point, reducing overheating problems.
  • Prevents corrosion of iron, steel, copper, brass, aluminum and welds.
  • Biodegradable.
  • Contains triethylene glycol; non-toxic.
  • Slightly hazardous to water; classified as WGK1 following self-assessment.

Technical data

Property Value
Appearance Red transparent liquid
Contents of triethylene glycol 90 % P/P
pH 50 % V/V 8 – 9

Approvals / Specifications

Corrosion protection

Glycol-water mixtures are more corrosive than pure water; they must be used with additives to protect the integrity of the system.

The results of the tests assessing the corrosion of various metals, carried out in accordance with the ASTM D 1384 standard, are shown below.

Material Thermosol® Concentrate 50 % V/V ASTM D 3306 max.
Copper 0.5 10
Solder 0.1 30
Brass −0.5 10
Mild steel −1.0 10
Cast iron −3.7 10
Aluminum 2.0 30

The results are expressed in mg/coupon. A negative result indicates an increase in weight due to the formation of a stable protective layer on the metal’s surface.

Description of the ASTM D 1384 test: in this test method, samples made from metals typically found in engine cooling systems are completely immersed in aerated solutions of engine coolant mixed with corrosive water for 336 hours at 88 °C. The anti-corrosion properties of the test solution are assessed on the basis of changes in the weight of the samples. Each test is carried out in triplicate and the average change in weight is determined for each metal.

Compatible materials

Thermosol® Concentrate is compatible with materials typically used in thermal circuits. The table below shows the plastics, sealants and elastomers that are compatible with the product. The data is taken from specialist literature and our own tests.

Compatibility with elastomers

Material 25 °C 80 °C 160 °C
Adiprene™ L-100 OK NR NR
Black Rubber 3773 OK NR NR
Buna N (o 25) OK OK —
Buna S OK Acceptable NR
Butyl Rubber OK OK —
Compressed Asbestos OK OK Acceptable
EPDM OK OK OK
EPR Rubber OK OK OK
Hycar™ D-24 OK Acceptable —
Hypalon™ OK NR NR
Kalrez™ OK OK OK
Natural Rubber Gum OK NR NR
Neoprene 7797 OK Acceptable —
Red Rubber 107 OK NR NR
Saraloy™ 300 OK NR NR
Silicone No. 65 OK OK —
Thiokol™ 3060 OK NR NR
Viton™ A OK OK NR

OK: recommended · NR: not recommended · —: no data.

Phenolic resins, plasticised PVC and polyurethanes are not compatible with Thermosol® and its mixtures with water.

Zinc is not compatible with triethylene glycol or its mixtures with water; avoid using zinc-coated tanks.

If there is galvanised material in the system, a whitish sediment will initially appear as the zinc dissolves and precipitates as oxide. Once this solid has been removed, the exposed carbon steel will be protected by Thermosol® within the specified dosage range without requiring any further action on the system.

Thermophysical tables

Thermodynamic properties of Thermosol® Concentrate dilutions in water as a function of temperature.

Thermosol® 30 % V/V
Temperature
°C
Density
kg/m³
Specific heat
kJ/kg·K
Thermal conductivity
W/m·K
Dynamic viscosity
mPa·s
Kinematic viscosity
mm²/s
Prandtl number Vapor pressure
mbar
−10 1,064.3 3.67 0.471 9.38 8.82 73.03 3
0 1,059.3 3.68 0.474 5.45 5.14 42.31 6
10 1,054.3 3.70 0.476 3.71 3.52 28.88 11
20 1,049.3 3.72 0.478 2.76 2.63 21.51 22
30 1,044.3 3.74 0.479 2.17 2.08 16.93 40
40 1,039.3 3.77 0.481 1.77 1.70 13.84 70
50 1,034.3 3.79 0.483 1.48 1.43 11.64 117
60 1,029.3 3.82 0.485 1.27 1.23 9.99 189
70 1,024.3 3.84 0.486 1.10 1.08 8.73 296
80 1,019.3 3.87 0.488 0.97 0.96 7.73 450
90 1,014.3 3.90 0.490 0.87 0.86 6.92 666
100 1,009.3 3.93 0.492 0.78 0.77 6.25 963
110 1,004.3 3.97 0.493 0.71 0.71 5.70 1,362
120 999.3 4.00 0.495 0.65 0.65 5.23 1,887
130 994.3 4.04 0.497 0.59 0.60 4.83 2,568
140 989.3 4.07 0.499 0.55 0.55 4.48 3,437
150 984.3 4.11 0.500 0.51 0.52 4.18 4,530
160 979.3 4.15 0.502 0.47 0.48 3.92 5,886
170 974.3 4.19 0.504 0.44 0.45 3.69 7,547
180 969.3 4.24 0.505 0.42 0.43 3.48 9,560
Thermosol® 35 % V/V
Temperature
°C
Density
kg/m³
Specific heat
kJ/kg·K
Thermal conductivity
W/m·K
Dynamic viscosity
mPa·s
Kinematic viscosity
mm²/s
Prandtl number Vapor pressure
mbar
−14 1,072.4 3.55 0.452 13.64 12.72 107.22 2
−10 1,070.4 3.56 0.453 10.89 10.17 85.59 3
0 1,065.4 3.58 0.455 6.86 6.44 54.04 6
10 1,060.4 3.61 0.456 4.77 4.50 37.69 11
20 1,055.4 3.63 0.457 3.53 3.34 28.02 22
30 1,050.4 3.65 0.458 2.73 2.60 21.78 40
40 1,045.4 3.68 0.459 2.18 2.09 17.50 69
50 1,040.4 3.71 0.460 1.79 1.72 14.43 116
60 1,035.4 3.74 0.461 1.50 1.45 12.15 187
70 1,030.4 3.77 0.462 1.28 1.24 10.40 292
80 1,025.4 3.80 0.463 1.10 1.07 9.03 444
90 1,020.4 3.83 0.464 0.96 0.94 7.93 658
100 1,015.4 3.87 0.465 0.85 0.83 7.04 951
110 1,010.4 3.90 0.466 0.75 0.74 6.30 1,344
120 1,005.4 3.94 0.467 0.67 0.67 5.69 1,863
130 1,000.4 3.98 0.468 0.61 0.61 5.16 2,536
140 995.4 4.02 0.469 0.55 0.55 4.72 3,394
150 990.4 4.06 0.470 0.50 0.51 4.34 4,473
160 985.4 4.10 0.471 0.46 0.47 4.00 5,811
170 980.4 4.14 0.472 0.42 0.43 3.71 7,451
180 975.4 4.19 0.473 0.39 0.40 3.46 9,439
Thermosol® 40 % V/V
Temperature
°C
Density
kg/m³
Specific heat
kJ/kg·K
Thermal conductivity
W/m·K
Dynamic viscosity
mPa·s
Kinematic viscosity
mm²/s
Prandtl number Vapor pressure
mbar
−20 1,081.6 3.43 0.251 29.29 27.08 400.58 1
−10 1,076.6 3.46 0.251 16.15 15.00 222.13 3
0 1,071.6 3.48 0.252 9.85 9.19 136.32 5
10 1,066.6 3.51 0.252 6.46 6.05 89.97 11
20 1,061.6 3.54 0.252 4.46 4.21 62.66 21
30 1,056.6 3.57 0.252 3.22 3.05 45.50 39
40 1,051.6 3.60 0.252 2.40 2.28 34.16 68
50 1,046.6 3.63 0.252 1.83 1.75 26.35 114
60 1,041.6 3.66 0.253 1.44 1.38 20.80 184
70 1,036.6 3.69 0.253 1.15 1.11 16.73 288
80 1,031.6 3.73 0.253 0.93 0.90 13.69 438
90 1,026.6 3.76 0.253 0.76 0.74 11.36 648
100 1,021.6 3.80 0.253 0.64 0.62 9.54 937
110 1,016.6 3.84 0.253 0.54 0.53 8.10 1,325
120 1,011.6 3.88 0.254 0.45 0.45 6.95 1,836
130 1,006.6 3.92 0.254 0.39 0.39 6.02 2,499
140 1,001.6 3.96 0.254 0.34 0.34 5.25 3,344
150 996.6 4.00 0.254 0.29 0.29 4.61 4,407
160 991.6 4.05 0.254 0.26 0.26 4.08 5,726
170 986.6 4.09 0.254 0.23 0.23 3.63 7,343
180 981.6 4.14 0.255 0.20 0.20 3.25 9,301
Thermosol® 45 % V/V
Temperature
°C
Density
kg/m³
Specific heat
kJ/kg·K
Thermal conductivity
W/m·K
Dynamic viscosity
mPa·s
Kinematic viscosity
mm²/s
Prandtl number Vapor pressure
mbar
−27 1,093.6 3.30 0.413 75.49 69.03 603.47 0
−20 1,090.1 3.32 0.413 42.37 38.87 340.30 1
−10 1,085.1 3.35 0.414 21.81 20.10 176.37 2
0 1,080.1 3.38 0.415 12.72 11.78 103.63 5
10 1,075.1 3.41 0.415 8.08 7.52 66.34 11
20 1,070.1 3.44 0.416 5.46 5.11 45.19 21
30 1,065.1 3.47 0.416 3.87 3.63 32.28 38
40 1,060.1 3.50 0.417 2.85 2.68 23.92 67
50 1,055.1 3.54 0.417 2.16 2.04 18.27 112
60 1,050.1 3.57 0.418 1.67 1.59 14.31 181
70 1,045.1 3.61 0.419 1.33 1.27 11.44 283
80 1,040.1 3.65 0.419 1.07 1.03 9.31 430
90 1,035.1 3.69 0.420 0.88 0.85 7.69 637
100 1,030.1 3.73 0.420 0.73 0.70 6.43 921
110 1,025.1 3.77 0.421 0.61 0.59 5.45 1,302
120 1,020.1 3.81 0.421 0.52 0.51 4.66 1,805
130 1,015.1 3.85 0.422 0.44 0.43 4.03 2,456
140 1,010.1 3.89 0.423 0.38 0.38 3.50 3,287
150 1,005.1 3.94 0.423 0.33 0.33 3.07 4,332
160 1,000.1 3.98 0.424 0.29 0.29 2.71 5,629
170 995.1 4.03 0.424 0.25 0.26 2.41 7,218
180 990.1 4.08 0.425 0.22 0.23 2.16 9,143
Thermosol® 50 % V/V
Temperature
°C
Density
kg/m³
Specific heat
kJ/kg·K
Thermal conductivity
W/m·K
Dynamic viscosity
mPa·s
Kinematic viscosity
mm²/s
Prandtl number Vapor pressure
mbar
−36 1,104.5 3.16 0.392 324.99 294.24 2,621.41 0
−30 1,101.5 3.18 0.392 166.25 150.93 1,346.39 0
−20 1,096.5 3.21 0.393 61.37 55.97 501.11 1
−10 1,091.5 3.24 0.394 29.40 26.93 242.06 2
0 1,086.5 3.27 0.394 16.39 15.09 136.16 5
10 1,081.5 3.31 0.395 10.10 9.34 84.66 11
20 1,076.5 3.34 0.395 6.68 6.21 56.50 21
30 1,071.5 3.38 0.396 4.66 4.35 39.75 38
40 1,066.5 3.41 0.396 3.38 3.17 29.13 66
50 1,061.5 3.45 0.397 2.54 2.39 22.06 110
60 1,056.5 3.49 0.398 1.96 1.85 17.15 177
70 1,051.5 3.53 0.398 1.54 1.46 13.64 278
80 1,046.5 3.57 0.399 1.23 1.18 11.05 422
90 1,041.5 3.61 0.399 1.01 0.97 9.09 624
100 1,036.5 3.65 0.400 0.83 0.80 7.59 902
110 1,031.5 3.69 0.400 0.70 0.67 6.41 1,276
120 1,026.5 3.74 0.401 0.59 0.57 5.48 1,768
130 1,021.5 3.78 0.402 0.50 0.49 4.72 2,407
140 1,016.5 3.83 0.402 0.43 0.42 4.11 3,221
150 1,011.5 3.87 0.403 0.37 0.37 3.60 4,245
160 1,006.5 3.92 0.403 0.33 0.32 3.17 5,516
170 1,001.5 3.97 0.404 0.29 0.29 2.82 7,073
180 996.5 4.02 0.404 0.25 0.25 2.52 8,960
Thermosol® 55 % V/V
Temperature
°C
Density
kg/m³
Specific heat
kJ/kg·K
Thermal conductivity
W/m·K
Dynamic viscosity
mPa·s
Kinematic viscosity
mm²/s
Prandtl number Vapor pressure
mbar
−46 1,118.3 2.99 0.383 12,815.50 11,459.81 100,000.43 0
−40 1,115.3 3.01 0.383 1,914.77 1,716.82 15,045.90 0
−30 1,110.3 3.04 0.382 277.58 250.00 2,212.12 0
−20 1,105.3 3.08 0.381 89.00 80.52 719.43 1
−10 1,100.3 3.11 0.379 39.62 36.01 324.93 2
0 1,095.3 3.15 0.378 21.13 19.29 175.83 5
10 1,090.3 3.18 0.377 12.64 11.59 106.70 10
20 1,085.3 3.22 0.376 8.18 7.54 70.10 20
30 1,080.3 3.26 0.375 5.61 5.19 48.80 37
40 1,075.3 3.30 0.374 4.02 3.74 35.52 64
50 1,070.3 3.34 0.372 2.99 2.79 26.78 107
60 1,065.3 3.38 0.371 2.28 2.14 20.77 173
70 1,060.3 3.42 0.370 1.79 1.68 16.49 271
80 1,055.3 3.46 0.369 1.42 1.35 13.36 412
90 1,050.3 3.51 0.368 1.15 1.10 11.00 609
100 1,045.3 3.55 0.367 0.95 0.91 9.20 881
110 1,040.3 3.59 0.366 0.79 0.76 7.78 1,245
120 1,035.3 3.64 0.364 0.67 0.64 6.66 1,726
130 1,030.3 3.68 0.363 0.57 0.55 5.76 2,349
140 1,025.3 3.73 0.362 0.49 0.47 5.02 3,144
150 1,020.3 3.78 0.361 0.42 0.41 4.41 4,143
160 1,015.3 3.83 0.360 0.37 0.36 3.90 5,383
170 1,010.3 3.88 0.359 0.32 0.32 3.48 6,903
180 1,005.3 3.93 0.357 0.28 0.28 3.12 8,745

Directions for use

Before filling, the circuit must be rinsed with water to remove any dirt, assembly residues and fluxes, particularly those containing chlorides, fluorides or borax.

Following the pressure test – which may be carried out to assess the circuit’s volume based on the volume of water used (as measured by the meter) – the circuit must be drained and immediately filled with antifreeze. Any air bubbles must be removed immediately.

Avoid leaving the circuit empty between the pressure test and subsequent filling, as this affects the circuit components, particularly carbon steel and cast iron.

In the case of a circuit already in use, after draining the previous antifreeze, it must be flushed with water to remove sediment and particles before filling the system with Thermosol® Concentrate. Existing corrosion can significantly shorten the product’s service life. If corrosion is detected, corrective measures must be taken before filling the system. Depending on the condition of the previous fluid, it is recommended to clean the circuit before filling it, for example, with Luzar® Clean Cool or CS-LTV.

It is recommended to use Teflon or hemp tape to seal threaded joints. Check the compatibility of other products with monoethylene glycol before using them.

Thermosol® Concentrate is a concentrated product that must be diluted before use. The minimum concentration required to ensure its anti-corrosion properties is 40 per cent. The maximum recommended concentration is 55 per cent. In aluminum-free systems, the dosage can be reduced to as low as 30 per cent.

It is recommended to use demineralized water if tap water is not fit for drinking or has a chloride content exceeding 100 ppm. We advise you to familiarize yourself with the legal requirements regarding the quality of the water used to dilute the antifreeze in the jurisdiction where your business operates.

Mixing with other types of antifreeze should be avoided to prevent any incompatibility that would reduce the product’s service life. For specific compatibility issues, please contact our technical department by email at carpemar@carpemar.com.

The system must not be left inactive for long periods of time, and the antifreeze must not be allowed to stand in the circuit or be subjected to thermal stress, as this may affect the stability of the product and, consequently, significantly shorten its service life.

To prepare the mixture in the correct proportions, depending on the desired temperature, pour the water and antifreeze into a sufficiently large container and stir the mixture until a homogeneous solution is obtained.

The mixture can also be prepared within the circuit whilst keeping the pump running with all circuits open, until a refractometer confirms that the glycol concentration is as calculated. Leave the pump running for at least long enough for the total volume of the system to circulate through it 3.5 times.

Thermosol® Concentrate (% V/V) Freezing temperature (°C) Protection temperature (°C)
30 −10 −14
35 −14 −18
40 −20 −24
45 −27 −30
50 −36 −38
55 −46 −48

The freezing point according to ASTM D 1177 is the temperature at which the first ice crystal forms. The DIN 51583 standard defines the temperature at which the product ceases to flow and there is a risk to the integrity of the circuit. Between these two temperatures, there is a mixture of ice crystals and unfrozen fluid which flows without increasing in volume and, therefore, without any risk of rupture.

Refractometer measurements

Burst temperature (°C) % Propylene glycol °Brix
−17 34.9 25.08
−22 41.8 28.54
−27 48.7 32.00
−34 55.6 35.45
−41 62.5 38.91
−49 69.4 42.36

The refractometer readings are intended for a refractometer whose scale does not include values for triethylene glycol, the base glycol in Thermosol® concentrated. Carpemar® offers a refractometer whose scale includes values for triethylene glycol, propylene glycol and monoethylene glycol.

Minor corrosion damage may become more visible after filling with Thermosol® due to the product’s lower surface tension compared with that of water.

Operating temperature

The product is stable at temperatures from the freezing point to 190 °C. Temperatures above 200 °C may affect the product, reducing its service life.

In the case of open systems or where oxygen is introduced (for example, via valves), the maximum operating temperature is lower.

Maintenance – Service life

The service life of Thermosol® Concentrate mixed with water is at least five years in a closed circuit operating between the freezing point and 100 °C. Field experience shows that the fluid does not degrade under the anticipated operating conditions, resulting in a longer service life.

To check the product’s performance, pH and glycol concentration measurements are the key parameters. It is recommended that these values be checked annually.

The glycol content must not deviate from the initial value. The correct pH range is between 7.5 and 9.0. If the pH falls outside this range, the product must be analyzed to determine the cause and the appropriate course of action.

Dosage

Precautions

Thermosol® Concentrate and its dilutions are non-flammable and non-corrosive products. They are non-toxic. In any case, it is recommended to follow good craft and industrial practices.

Avoid contact with the eyes. In the event of contact, rinse the eye with plenty of water for 10 minutes. Do not swallow and keep out of the reach of children.

Store in a cool, well-ventilated place. Thermosol® Concentrate and its dilutions remain in good condition for at least two years at temperatures between 10 and 40 °C, provided they are kept away from direct sunlight and stored in airtight, tightly sealed containers.

Downloadable documents

Find all the relevant documentation about the product: technical data sheets and safety data sheets.

Thermosol Concentrate

Documentación en Español
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Technical data sheet

Safety data sheet